Last 'Big Names to team up and win the tag titles' was Show and Kane in April 2011. Though you'd argue they weren't working on top at the time.
John Cena & The Miz were in the midst of their Mania feud when they won the titles together in February 2011. They lost them on the same show.
Personally I hate the whole deal with main event guys winning the tag belts.
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