Villians in movies/tv you liked
 

Benny from The mummy

Darth Vader - Star Wars series
Agent Smith - The Matrix series
Gollum - Lord of the Rings series
The Scarecrow/Dr. Jonathon Crane - Batman Begins
Bricktop - Snatch
Starscream - Transformers
Skeletor - He-Man and the Masters of the Universe
The Shredder - Teenage Mutant Ninja Turtles
Syndrome - The Incredibles
The Borg - Star Trek
The Dominion - Star Trek
Lex Luthor - Superman Returns
Spike, Angelus and Drusilla (all together... excellent dynamics as a villain team) - Buffy The Vampire Slayer
Doctor Octopus - Spider-Man 2
Mom - Futurama
Kevin - Sin City
Barbossa - Pirates of the Caribbean: Curse of the Black Pearl
Reese Feldman - Starsky and Hutch
Magneto - X-Men series
Wes Mantooth - Anchorman
Commodus - Gladiator
Lord Voldemort - Harry Potter and the Goblet of Fire
The StayPuft Marshmallow Man - Ghostbusters
Dr. Evil - Austin Powers series
Saruman The White - Lord of the Rings series
Col. William Tavington - The Patriot
Dr. Bob Kelso - Scrubs
Vego the Carpathian - Ghostbusters II
Zombies - Dawn of the Dead remake

That'll probably do for now. :$ I might add more if I think of 'em. :$

Off the top of my head, Top Dollar from The crow is a damn underrated villain. Also T-Bird, Tin Tin, Funboy, and Skank from the same film.

And Luther from The Warriors.

Sheriff Lucas Buck - American Gothic

Tony Perkis - Heavyweights

Boondock saint reminded me:

Il Duce from Boondock Saints :S

Doctor Kelso - Scrubs

Any villain Alan Rickman has ever played

Lex Luthor - Superman Returns
Bellick - Prison Break is cool too.

Johnny Casper and Eddie Dane - Miller's Crossing
Henri Ducard/Ra'as Algoo - Batman Begins

:y:

:y:

The Joker - Batman
The Penguin - Batman
Col. William Tavington - The Patriot
Lucius Malfoy - Harry Potter Movies
Agent Smith - The Matrix Trilogy
T-1000 - T2: Judgement Day
Darth Vader - Star Wars
Frank Costello - The Departed
Prince Lotor - Voltron: Defender of the Universe
Magneto - X-Men Trilogy
Angel Eyes - The Good, the Bad, and the Ugly
Frank Nitty - The Untouchables


More to come......

John Kramer (Jigsaw) - Saw 1/2/3.

Although I don't know if you could really call him a villain though, to be honest.

Bricktop

Deacon Frost - Blade 1

The Pin and Tugger from Brick

John Kramer (Jigsaw) - Saw 1/2/3.

Otis, Spaulding and Baby: Devils Rejects

Dark Helmet and Colonel Sanders.

Jafar immediately came to mind. Even though I didn't even really like him but the movie Aladdin was sick so I will say Jafar.

Ben in Lost
Rita and Lord Zed from Power Rangers

The guy coming the desert with the afro pick...

Ghost - Ginger Snaps 2

Patience Iago

Apocalypse from the X-Men series