Kill Bill Vol. 1 - "I want them to know. I WANT them to know. I want them to know that they'll all soon be as dead as O'Ren!"
Kill Bill Vol. 2 - That whole Five Point Palm Exploding Heart Technique thing at the end with Bill. That was so great.
Cabin Fever - "PANCAAAAAAAAAAAAKES!" Enough said.
Donnie Darko - Although it wasn't on the VHS version, I love the scene at the end that shows Donnie lying on the bed slowly dying with a big piece of wood stuck through his chest. Also, any part of it with Frank. Frank is tits.
Resident Evil: Apocalypse - The whole thing with the Umbrella Corporation and the civilians of Raccoon City. Just watching them close the gates off gave me chills, since you knew what they were doing. Nemesis was great too, although the fact that he had feelings was a turnoff.
Star Wars Episode Three - "NOOOOOOOOOOOOOOOOOOOOOOOOOOOOO!"
American History X - Curb Stomp. 'Nuf said.